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GOULAY RESEARCH GROUP
Laser Spectroscopy and Gas Phase Kinetics

Publications

JPCA 2024



(48)  Rutto P., Ubana E., Selby M. S., Goulay F. "Kinetic Study of OH Radical Reactions with Cyclopentenone derivatives", Journal of Physical Chemistry A 2024




Selby et al.
(47)  Selby M. S., Goulay F., Soorkia S., Ray A., Jasper A. W., Klippenstein S. J., Morozov N., Mebel A. M., Savee J. D., Taatjes C. A., Osborn D. L. "Radial-Radical Reactions in Molecular Weight Growth: The Phenyl + Propargyl Reaction", Journal of Physical Chemistry A 2023, 127, 2577-2590


JPCA 2023


(46)  Masaya T. W. and Goulay F.  "A Molecular Dynamic Study of the Effects of Surface Partitioning on the OH Radical Interactions with Solutes in Multicomponent Aqueous Aerosols",   Journal of Physical Chemistry A 2023 , 127, 751-764





TOC JPCA 2022
(45)  Caster K. L., Lee, J., Donnelan Z.,  Selby T. L., Osborn D. L., Goulay F.  "Formation  of a resonance-stabilized radical intermediate by hydroxyl radical addition to cyclopentadiene",   Journal of Physical Chemistry A  2022, 126, 9031-9041



andres et al


(44) Andrés J., Safont V. S., Oliva M., Caster, K. L. , Goulay F. " A bonding evolution theory study of the reaction between methylidyne radical, CH(X2Π), and cyclopentadiene, C5H6", International Journal of Quantum Chemistry 2022, 122:e26892





JPCA 2021

(43)  Caster K. L., Selby, T. L., Osborn D. L., Le Picard S. D, Goulay, F.  "Product Detection of the CH (X2Π) Radical Reaction with Cyclopentadiene: Novel Route to Benzene",  Journal of Physical Chemistry A  2021,125, 6927-6939



Lee et al Spectra

(42) Lee, J., Caster, K. L., Maddaleno, T, Donnellan, Z. N., Selby, T. M., Goulay, F. "Kinetic study of the CN radical reaction with 2-methylfuran", International Journal of Chemical Kinetics 202052, 838-851. 




Atmosphere TOC


(41) Fan, H. and Goulay, F. " Effect of Bulk Composition on the Heterogeneous Oxidation of Semi-Solid Atmospheric Aerosols ", Atmosphere 2019, 10, 791 (1-17)




JPCA 2019 Caster


(40)  Caster, K. L., Donnellan, Z. N., Selby, T. L., Goulay, F.  "Kinetic Investigations of the CH (X2Π) Radical Reaction with Cyclopentadiene",  Journal of Physical Chemistry A 2019, 123, 5692-5703



JPCA amines


(39) Bourgalais, J., Caster, K. L., Durif, O., Osborn, D. L., Le Picard, S. R., and Goulay, F. "Product Detection of the CH Radical Reactions With Ammonia and Methyl-Substituted Amines" Journal of Physical Chemistry A 2019, 123, 2178-2193



Partitioning

(38) Fan, H, Masaya, T. W., and Goulay F. "Effect of surface-bulk partitioning 
on the heterogeneous oxidation of aqueous saccharide aerosols"  Physical Chemistry Chemical Physics   2019,  21, 2992-3001

C+butene

(37) Bourgalais, J.; Spencer, M.; Osborn, D. L.; Goulay, F. and Le Picard, S. D. "Reactions of atomic carbon with butene isomers: implications for molecular growth in carbon-rich environments" Journal of Physical Chemistry A 2016, 120, 9138-9150

PCCP pers36) Trevitt, A. J. and Goulay, F. "Insights into gas-phase reaction mechanisms of small carbon radicals using isomer-resolved product detection" Physical Chemistry Chemical Physics 2016, 18, 5867-5882.


JPCL


(35) Thapa, J.; Spencer, M.; Akhmedov, N. G. and Goulay, F. "Kinetics of the OH Radical Reaction with Fulvenallene from 298 to 450K" Journal of Physical Chemistry Letters 2015, 6, 4997-5001.




hetero(34) Fan, H. Y.; Tinsley, M. R. and Goulay, F. "Effect of Relative Humidity on the OH-Initiated Heterogeneous Oxidation of Monosaccharide Nanoparticles" Journal of Physical Chemistry A 2015, 119, 11182-11190.

( C C3H633) Capron, M.; Bourgalais, J.; Kailasanathan, R. K. A.; Osborn, D. L.; Le Picard, S. D. and Goulay, F. "Flow tube studies of the C(P-3) reactions with ethylene and propylene" Physical Chemistry Chemical Physics 2015, 17, 23833-23846.



NH3II(32) Hickson, K. M.; Loison, J. C.; Bourgalais, J.; Capron, M.; Le Picard, S. D.; Goulay, F. and Wakelam, V. "The C(P-3) reaction in interstellar chemistry. II. Low temperature rate constants and modeling of NH, NH2, and NH3 abundances in dense interstellar clouds" Astrophysical Journal 2015, 812.


NH3I(31) Bourgalais, J.; Capron, M.; Kailasanathan, R. K. A.; Osborn, D. L.; Hickson, K. M.; Loison, J. C.; Wakelam, V.; Goulay, F. and Le Picard, S. D. "The C(P-3) + NH3 reaction in interstellar chemistry. I. Investigation of the product formation channeles" Astrophysical Journal 2015, 812.


ph
(30) Kailasanathan, R. K. A.; Thapa, J. and Goulay, F. "Kinetic Study of the OH Radical Reaction with Phenylacetylene" Journal of Physical Chemistry A 2014, 118, 7732-7741.


cellulose

(29) Seehra, M. S.; Popp, B. V.; Goulay, F.; Pyapalli, S. K.; Gullion, T. and Poston, J. "Hydrothermal treatment of microcrystalline cellulose under mild conditions: characterization of solid and liquid-phase products" Cellulose 2014, 21, 4483-4495.




propene(28) Trevitt, A. J.; Prendergast, M. B.; Goulay, F.; Savee, J. D.; Osborn, D. L.; Taatjes, C. A. and Leone, S. R. "Product Branching Fractions of the CH plus Propene Reaction from Synchrotron Photoionization Mass Spectrometry" Journal of physical chemistry A 2013, 117, 6450-6457.

acrolein

(27) Lockyear, J. F.; Welz, O.; Savee, J. D.; Goulay, F.; Trevitt, A. J.; Taatjes, C. A.; Osborn, D. L. and Leone, S. R. "Isomer Specific Product Detection in the Reaction of CH with Acrolein" Journal of physical chemistry A 2013, 117, 11013-11026.



acetonr(26) Goulay, F.; Derakhshan, A.; Maher, E.; Trevitt, A. J.; Savee, J. D.; Scheer, A. M.; Osborn, D. L. and Taatjes, C. A. "Formation of dimethylketene and methacrolein by reaction of the CH radical with acetone" Physical Chemistry Chemical Physics 2013, 15, 4049-4058.

Fabien's publications before WVU

soot(25) Goulay, F.; Schrader, P. E.; Lopez-Yglesias, X. and Michelsen, H. A. "A data set for validation of models of laser-induced incandescence from soot: temporal profiles of LII signal and particle temperature" Applied Physics B-Lasers and Optics 2013, 112, 287-306.


acethaldheyde(24) Goulay, F.; Trevitt, A. J.; Savee, J. D.; Bouwman, J.; Osborn, D. L.; Taatjes, C. A.; Wilson, K. R. and Leone, S. R. "Product Detection of the CH Radical Reaction with Acetaldehyde" Journal of physical chemistry A 2012, 116, 6091-6106.

laval(23) Bouwman, J.; Goulay, F.; Leone, S. R. and Wilson, K. R. "Bimolecular Rate Constant and Product Branching Ratio Measurements for the Reaction of C2H with Ethene and Propene at 79 K" Journal of physical chemistry A 2012, 116, 3907-3917.

Hed(22) Headrick, J. M.; Goulay, F.; Schrader, P. E. and Michelsen, H. A. "High-vacuum time-resolved laser-induced incandescence of flame-generated soot" Applied Physics B-Lasers and Optics 2011, 104, 439-450.


C2Hallene(21) Goulay, F.; Soorkia, S.; Meloni, G.; Osborn, D. L.; Taatjes, C. A. and Leone, S. R. "Detection of pentatetraene by reaction of the ethynyl radical (C2H) with allene (CH2=C=CH2) at room temperature" Physical Chemistry Chemical Physics 2011, 13, 20820-20827.

CN toluene
(20) Trevitt, A. J.; Goulay, F.; Taatjes, C. A.; Osborn, D. L. and Leone, S. R. "Reactions of the CN Radical with Benzene and Toluene: Product Detection and Low-Temperature Kinetics" Journal of physical chemistry A 2010, 114, 1749-1755.

ILALS
(19) Strasser, D.; Goulay, F.; Belau, L.; Kostko, O.; Koh, C.; Chambreau, S. D.; Vaghjiani, G. L.; Ahmed, M. and Leone, S. R. "Tunable Wavelength Soft Photoionization of Ionic Liquid Vapors" Journal of physical chemistry A 2010, 114, 879-883.


carbon

(18) Michelsen, H. A.; Schrader, P. E. and Goulay, F. "Wavelength and temperature dependences of the absorption and scattering cross sections of soot" Carbon 2010, 48, 2175-2191.



isoprene(17) Greenwald, E. E.; Ghosh, B.; Anderson, K. C.; Dooley, K. S.; Zou, P.; Selby, T.; Osborn, D. L.; Meloni, G.; Taatjes, C. A.; Goulay, F. and North, S. W. "Isomer-Selective Study of the OH Initiated Oxidation of Isoprene in the Presence of O-2 and NO. I. The Minor Inner OH-Addition Channel" Journal of physical chemistry A 2010, 114, 904-912.


( Emsoot16) Goulay, F.; Schrader, P. E. and Michelsen, H. A. "Effect of the wavelength dependence of the emissivity on inferred soot temperatures measured by spectrally resolved laser-induced incandescence" Applied Physics B-Lasers and Optics 2010, 100, 655-663.


MolecPhys

(15) Goulay, F.; Nemes, L.; Schrader, P. E. and Michelsen, H. A. "Spontaneous emission from C-2(d (3)Pi g) and C-3(A (1)Pi(u)) during laser irradiation of soot particles" Molecular Physics 2010, 108, 1013-1025.


CNpropene(14) Trevitt, A. J.; Goulay, F.; Meloni, G.; Osborn, D. L.; Taatjes, C. A. and Leone, S. R. "Isomer-specific product detection of CN radical reactions with ethene and propene by tunable VUV photoionization mass spectrometry" Int J Mass Spectrom 2009, 280, 113-118.


JACS(13) Goulay, F.; Trevitt, A. J.; Meloni, G.; Selby, T. M.; Osborn, D. L.; Taatjes, C. A.; Vereecken, L. and Leone, S. R. "Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons" Journal of the American Chemical Society 2009, 131, 993-1005.

ProcCombInst
(12) Goulay, F.; Schrader, P. E.; Nemes, L.; Dansson, M. A. and Michelsen, H. A. "Photochemical interferences for laser-induced incandescence of flame-generated soot" Proceedings of the Combustion Institute 2009, 32, 963-970.

Jitter(11) Goulay, F.; Schrader, P. E. and Michelsen, H. A. "The effects of pulsed laser injection seeding and triggering on the temporal behavior and magnitude of laser-induced incandescence from soot" Applied Physics B-Lasers and Optics 2009, 96, 613-621.


Selby(10) Selby, T. M.; Meloni, G.; Goulay, F.; Leone, S. R.; Fahr, A.; Taatjes, C. A. and Osborn, D. L. "Synchrotron photoionization mass spectrometry measurements of kinetics and product formation in the allyl radical (H2CCHCH2) self-reaction" Journal of physical chemistry A 2008, 112, 9366-9373.

Br2

(9) Strasser, D.; Goulay, F. and Leone, S. R. "Transient photoelectron spectroscopy of the dissociative Br-2((IIu)-I-1) state" Journal of Chemical Physics 2007, 127.


IoLiffemto
(8) Strasser, D.; Goulay, F.; Kelkar, M. S.; Maginn, E. J. and Leone, S. R. "Photoelectron spectrum of isolated ion-pairs in ionic liquid vapor" Journal of physical chemistry A 2007, 111, 3191-3195.


Melonie Jacs
(7) Meloni, G.; Selby, T. M.; Goulay, F.; Leone, S. R.; Osborn, D. L. and Taatjes, C. A. "Photoionization of 1-alkenylperoxy and alkylperoxy radicals and a general rule for the stability of their cations" Journal of the American Chemical Society 2007, 129, 14019-14025.

Polyynes(6) Goulay, F.; Osborn, D. L.; Taatjes, C. A.; Zou, P.; Meloni, G. and Leone, S. R. "Direct detection of polyynes formation from the reaction of ethynyl radical (C2H) with propyne (CH3-C CH) and allene (CH2 = C = CH2)" Physical Chemistry Chemical Physics 2007, 9, 4291-4300.


CHanth(5) Goulay, F.; Rebrion-Rowe, C.; Biennier, L.; Le Picard, S. D.; Canosa, A. and Rowe, B. R. "Reaction of anthracene with CH radicals: An experimental study of the kinetics between 58 and 470 K" Journal of physical chemistry A 2006, 110, 3132-3137.

C2H benzene
(4) Goulay, F. and Leone, S. R. "Low-temperature rate coefficients for the reaction of ethynyl radical (C2H) with benzene" Journal of physical chemistry A 2006, 110, 1875-1880.



OH anth(3) Goulay, F.; Rebrion-Rowe, C.; Le Garrec, J. L.; Le Picard, S. D.; Canosa, A. and Rowe, B. R. "The reaction of anthracene with OH radicals: An experimental study of the kinetics between 58 and 470 K" Journal of Chemical Physics 2005, 122.

HIDI(2) Goulay, F.; Rebrion-Rowe, C.; Carles, S.; Le Garrec, J. L. and Rowe, B. R. "Electron attachment on HI and DI in a uniform supersonic flow: Thermalization of the electrons" Journal of Chemical Physics 2004, 121, 1303-1308.

BC2H2
(1) Geppert, W. D.; Goulay, F.; Naulin, C.; Costes, M.; Canosa, A.; Le Picard, S. D. and Rowe, B. R. "Rate coefficients and integral cross-sections for the reaction of B(P-2(J)) atoms with acetylene" Physical Chemistry Chemical Physics 2004, 6, 566-571.



Book Chapters


CRESU book cover

Uniform Supersonic Flows in Chemical Physics Chemistry Close to Absolute Zero Studied Using the CRESU Method 
World Scientific, June 2022 
Edited By: Bertrand R Rowe, André Canosa and Dwayne E Heard 

Chapter 4: Study of Electron Attachment Reactions Using the CRESU Technique 
Fabien Goulay and Bertrand R. Rowe 
Pages:243–281 https://doi.org/10.1142/9781800610996_0004

Chapter 8: Low-Temperature Product Detection and Branching Ratios 
Sébastien D. Le Picard, Abdessamad Benidar and Fabien Goulay  Pages:435–477 https://doi.org/10.1142/9781800610996_0008


book
Low temperatures and cold molecules    
Imperial College Press, September 2008.  
Edited By: Iam W. M. Smith, I. W. M.

Chapter 2: Gas Phase Reactive Collisions at Very Low Temperature: Recent Experimental Advances and Perspectives 
André Canosa, Fabien Goulay, Ian R. Sims and Bertrand R. Rowe